Metal catalyzed C(sp3)–H bond amination of 2-alkyl azaarenes with diethyl azodicarboxylate

Jin-Ying Liu; Hong-Ying Niu; Shan Wu; Gui-Rong Qu; Hai-Ming Guo

doi:10.1039/C2CC35309A

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Metal catalyzed C(sp³)–H bond amination of 2-alkyl azaarenes with diethyl azodicarboxylate†

Jin-Ying Liu,^a Hong-Ying Niu,^b Shan Wu,^a Gui-Rong Qu*^a and Hai-Ming Guo*^a

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* Corresponding authors

^a College of Chemistry and Environmental Science, Key Laboratory of Green Chemical Media and Reactions of Ministry of Education, Henan Normal University, Xinxiang 453007, Henan, China
E-mail: quguir@sina.com, guohm518@hotmail.com
Fax: +86 373 3329276
Tel: +86 373 3329255

^b School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003, China

Abstract

Metal-catalyzed direct C(sp³)–H bond amination of 2-alkyl azaarenes with N [double bond, length as m-dash] N double bonds has been developed, which expands the scope of C(sp³)–H bond activation reactions and provides a new access to medicinally important azaarene derivatives.

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Article information

DOI: https://doi.org/10.1039/C2CC35309A
Article type: Communication
Submitted: 23 Jul 2012
Accepted: 14 Aug 2012
First published: 15 Aug 2012

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Chem. Commun., 2012,48, 9723-9725

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Metal catalyzed C(sp³)–H bond amination of 2-alkyl azaarenes with diethyl azodicarboxylate

J. Liu, H. Niu, S. Wu, G. Qu and H. Guo, Chem. Commun., 2012, 48, 9723 DOI: 10.1039/C2CC35309A

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