Issue 98, 2012
From the journal:

Chemical Communications

Counter-cation modulation of hydrogen and methane storage in a sodalite-type porous metal–organic framework†

Yun-Nan Gong,a   Miao Meng,a   Di-Chang Zhong,a   Yong-Liang Huang,a   Long Jianga  and  Tong-Bu Lu*a  

* Corresponding authors

a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: lutongbu@mail.sysu.edu.cn
Fax: +86-20-84112921

Abstract

A μ4-Cl bridged anionic sodalite-type porous metal–organic framework (Et2NH2)3[(Cu4Cl)3(TTCA)8]·26DEF was synthesized, in which Et2NH2+ can be exchanged by Li+ cations. The results of gas measurements indicate that Et2NH2+ and Li+ are beneficial for methane and hydrogen storage, respectively.

Graphical abstract: Counter-cation modulation of hydrogen and methane storage in a sodalite-type porous metal–organic framework

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Article information

DOI
https://doi.org/10.1039/C2CC35461F
Article type
Communication
Submitted
27 Jul 2012
Accepted
22 Oct 2012
First published
05 Nov 2012

Chem. Commun., 2012,48, 12002-12004

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Counter-cation modulation of hydrogen and methane storage in a sodalite-type porous metal–organic framework

Y. Gong, M. Meng, D. Zhong, Y. Huang, L. Jiang and T. Lu, Chem. Commun., 2012, 48, 12002 DOI: 10.1039/C2CC35461F

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