Issue 77, 2012
From the journal:

Chemical Communications

A carbazole-containing porphyrinoid: synthesis and oxidation to the porphyrin-state†

Lena Arnold,a   Martin Baumgartena  and  Klaus Müllen*a  

* Corresponding authors

a Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany
E-mail: muellen@mpip-mainz.mpg.de
Fax: +49 6131 379350
Tel: +49 6131 379150

Abstract

Carbazole-containing porphyrinoid 3 was synthesised for the first time via Suzuki–Miyaura cross-coupling reaction. Oxidation with MnO2 yielded its porphyrin-state 2 featuring macrocyclic aromaticity in exchange for the loss of the resonance energies of the benzene rings.

Graphical abstract: A carbazole-containing porphyrinoid: synthesis and oxidation to the porphyrin-state

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Article information

DOI
https://doi.org/10.1039/C2CC35550G
Article type
Communication
Submitted
31 Jul 2012
Accepted
09 Aug 2012
First published
09 Aug 2012

Chem. Commun., 2012,48, 9640-9642

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A carbazole-containing porphyrinoid: synthesis and oxidation to the porphyrin-state

L. Arnold, M. Baumgarten and K. Müllen, Chem. Commun., 2012, 48, 9640 DOI: 10.1039/C2CC35550G

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