Issue 87, 2012
From the journal:

Chemical Communications

Crystal engineering from a 1D chain to a 3D coordination polymer accompanied by a dramatic change in magnetic properties†

Yu-Chun Chuang,ab   Wei-Lun Ho,a   Chou-Fu Sheu,a   Gene-Hsiang Leec  and  Yu Wang*a  

* Corresponding authors

a Department of Chemistry, National Taiwan University, Taipei, Taiwan
E-mail: wangyu@ntu.edu.tw

b National Synchrotron Radiation Research Center, Hsinchu, Taiwan

c Instrumentation Center, College of Science, National Taiwan University, Taipei, Taiwan

Abstract

A unique structural transformation in the crystalline state assisted by coordination substitution is induced during a dehydration process. A 1D chain coordination polymer is irreversibly converted to a 3D interpenetrated network accompanied by a change in magnetic properties from a paramagnetic material to a spin crossover system.

Graphical abstract: Crystal engineering from a 1D chain to a 3D coordination polymer accompanied by a dramatic change in magnetic properties

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Article information

DOI
https://doi.org/10.1039/C2CC35879D
Article type
Communication
Submitted
14 Aug 2012
Accepted
12 Sep 2012
First published
18 Sep 2012

Chem. Commun., 2012,48, 10769-10771

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Crystal engineering from a 1D chain to a 3D coordination polymer accompanied by a dramatic change in magnetic properties

Y. Chuang, W. Ho, C. Sheu, G. Lee and Y. Wang, Chem. Commun., 2012, 48, 10769 DOI: 10.1039/C2CC35879D

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