Calixarene-supported clusters: employment of complementary cluster ligands for the construction of a ferromagnetic [Mn5] cage

Stephanie M. Taylor; Ruaraidh D. McIntosh; Stergios Piligkos; Scott J. Dalgarno; Euan K. Brechin

doi:10.1039/C2CC35944H

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Calixarene-supported clusters: employment of complementary cluster ligands for the construction of a ferromagnetic [Mn₅] cage†

Stephanie M. Taylor,^a Ruaraidh D. McIntosh,^b Stergios Piligkos,^c Scott J. Dalgarno*^b and Euan K. Brechin*^a

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* Corresponding authors

^a EaStCHEM School of Chemistry, The University of Edinburgh, West Mains Road, Scotland, Edinburgh, UK
E-mail: ebrechin@staffmail.ed.ac.uk
Fax: +44 (0)131-650-6453
Tel: +44 (0)131-650-7545

^b Institute of Chemical Sciences, Heriot – Watt University, Riccarton, Scotland, Edinburgh, UK
E-mail: S.J.Dalgarno@hw.ac.uk
Fax: +44 (0)131-451-3180
Tel: +44 (0)131-451-8025

^c Department of Chemistry, University of Copenhagen, Universitetsparken 5, DenmarkUK

Abstract

A combination of complementary cluster ligands results in the formation of a new calixarene-supported ferromagnetic [Mn₅] cage that displays the characteristic bonding modes of each support.

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Article information

DOI: https://doi.org/10.1039/C2CC35944H
Article type: Communication
Submitted: 16 Aug 2012
Accepted: 17 Sep 2012
First published: 05 Oct 2012

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Chem. Commun., 2012,48, 11190-11192

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Calixarene-supported clusters: employment of complementary cluster ligands for the construction of a ferromagnetic [Mn₅] cage

S. M. Taylor, R. D. McIntosh, S. Piligkos, S. J. Dalgarno and E. K. Brechin, Chem. Commun., 2012, 48, 11190 DOI: 10.1039/C2CC35944H

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