Issue 82, 2012
From the journal:

Chemical Communications

Ortho-substituent induced triradical-containing tetranuclear oxo-vanadium(iv) cluster formation vialigand C–N bond breaking and C–O bond making†‡

Samir Ghoraia  and  Chandan Mukherjee*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology, Guwahati, Assam, India
E-mail: cmukherjee@iitg.ernet.in
Fax: +91-361-258-2349
Tel: +91-361-258-2327

Abstract

Substituent having weak-coordination character, and attached at the ortho-carbon atom to the aniline moiety of 2-anilino-4,6-di-tert-butylphenol, provided a triradical-containing tetranuclear vanadium(IV) complex via ligand C–N bond breaking and C–O bond making.

Graphical abstract: Ortho-substituent induced triradical-containing tetranuclear oxo-vanadium(iv) cluster formation via ligand C–N bond breaking and C–O bond making

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Article information

DOI
https://doi.org/10.1039/C2CC35963D
Article type
Communication
Submitted
06 Jun 2012
Accepted
29 Aug 2012
First published
31 Aug 2012

Chem. Commun., 2012,48, 10180-10182

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Ortho-substituent induced triradical-containing tetranuclear oxo-vanadium(IV) cluster formation via ligand C–N bond breaking and C–O bond making

S. Ghorai and C. Mukherjee, Chem. Commun., 2012, 48, 10180 DOI: 10.1039/C2CC35963D

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