Issue 100, 2012
From the journal:

Chemical Communications

γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes†

Sean M. Smith,a   Gia L. Hoang,a   Rhitankar Pal,a   Mohammad O. Bani Khaled,a   Liberty S. W. Pelter,b   Xiao Cheng Zenga  and  James M. Takacs*a  

* Corresponding authors

a Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska, USA
E-mail: jtakacs1@unl.edu
Fax: +1 402 472-9402
Tel: +1 402 472-6232

b Department of Chemistry and Physics, Purdue University Calumet, Indiana, Hammond, USA

Abstract

Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90–95% ee).

Graphical abstract: γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes

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Article information

DOI
https://doi.org/10.1039/C2CC36199J
Article type
Communication
Submitted
26 Aug 2012
Accepted
31 Oct 2012
First published
01 Nov 2012

Chem. Commun., 2012,48, 12180-12182

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γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes

S. M. Smith, G. L. Hoang, R. Pal, M. O. B. Khaled, L. S. W. Pelter, X. C. Zeng and J. M. Takacs, Chem. Commun., 2012, 48, 12180 DOI: 10.1039/C2CC36199J

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