Issue 98, 2012
From the journal:

Chemical Communications

The synergistic effect of Rh–Ni catalysts on the highly-efficient dehydrogenation of aqueous hydrazine borane for chemical hydrogen storage†

Di-Chang Zhong,a   Kengo Aranishi,a   Ashish Kumar Singh,a   Umit B. Demircib  and  Qiang Xu*a  

* Corresponding authors

a National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Japan
E-mail: q.xu@aist.go.jp
Fax: +81 72 751 7942

b Institut Européen des Membranes (IEMM), Université Montpellier 2, ENSCM, CNRS, UMR5635, Place Eugène Bataillon, France

Abstract

An Rh4Ni alloy nanocatalyst exhibits highly-efficient performance in dehydrogenation of aqueous hydrazine borane. The hydrogen selectivity reaches almost 100%. More interestingly, catalyzed by the Rh4Ni nanocatalyst, the dehydrogenation of aqueous hydrazine borane is not simply divided into two steps.

Graphical abstract: The synergistic effect of Rh–Ni catalysts on the highly-efficient dehydrogenation of aqueous hydrazine borane for chemical hydrogen storage

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Article information

DOI
https://doi.org/10.1039/C2CC36407G
Article type
Communication
Submitted
03 Sep 2012
Accepted
27 Sep 2012
First published
27 Sep 2012

Chem. Commun., 2012,48, 11945-11947

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The synergistic effect of Rh–Ni catalysts on the highly-efficient dehydrogenation of aqueous hydrazine borane for chemical hydrogen storage

D. Zhong, K. Aranishi, A. K. Singh, U. B. Demirci and Q. Xu, Chem. Commun., 2012, 48, 11945 DOI: 10.1039/C2CC36407G

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