Susceptible electron spin adhering to an yttrium cluster inside an azafullerene C79N

Yihan Ma; Taishan Wang; Jingyi Wu; Yongqiang Feng; Li Jiang; Chunying Shu; Chunru Wang

doi:10.1039/C2CC36435B

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Susceptible electron spin adhering to an yttrium cluster inside an azafullerene C₇₉N†

Yihan Ma,^a Taishan Wang,*^a Jingyi Wu,^b Yongqiang Feng,^a Li Jiang,^a Chunying Shu^a and Chunru Wang*^a

Author affiliations

* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Beijing 100190, China
E-mail: wangtais@iccas.ac.cn, crwang@iccas.ac.cn
Fax: +86-10-62652120
Tel: +86-10-62652120

^b Laboratory of Nuclear Analysis Techniques, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, China

Abstract

Highly impressionable electron spin was found in endohedral azafullerene Y₂@C₇₉N at low temperature or upon exohedral chemical modification. These external stimulations can be employed to manipulate the spin-active Y₂@C₇₉N and can further be used in quantum processes for promising information-carrying spin systems and molecular devices.

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Article information

DOI: https://doi.org/10.1039/C2CC36435B
Article type: Communication
Submitted: 18 Jun 2012
Accepted: 16 Oct 2012
First published: 16 Oct 2012

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Chem. Commun., 2012,48, 11570-11572

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Susceptible electron spin adhering to an yttrium cluster inside an azafullerene C₇₉N

Y. Ma, T. Wang, J. Wu, Y. Feng, L. Jiang, C. Shu and C. Wang, Chem. Commun., 2012, 48, 11570 DOI: 10.1039/C2CC36435B

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Chemical Communications