1,5-Migration of rhodium via C–H bond activation in catalytic decyanative silylation of nitriles†
Abstract
Unprecedented aryl-to-aryl 1,5-rhodium migration is involved in decyanative
* Corresponding authors
a
Center for Atomic and Molecular Technologies, Graduate School of Engineering, Osaka University, Suita, Japan
E-mail:
tobisu@chem.eng.osaka-u.ac.jp
b
Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Japan
E-mail:
chatani@chem.eng.osaka-u.ac.jp
Unprecedented aryl-to-aryl 1,5-rhodium migration is involved in decyanative
M. Tobisu, J. Hasegawa, Y. Kita, H. Kinuta and N. Chatani, Chem. Commun., 2012, 48, 11437 DOI: 10.1039/C2CC36601K
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