Issue 93, 2012

1,5-Migration of rhodium via C–H bond activation in catalytic decyanative silylation of nitriles

Abstract

Unprecedented aryl-to-aryl 1,5-rhodium migration is involved in decyanative silylation of aryl cyanides bearing a tethered arene. The 1,5-migration proceeds through remote C–H bond activation. 1,5-Migration also occurs in other rhodium-catalyzed reactions, including borylation and oxidative Mizoroki–Heck reactions.

Graphical abstract: 1,5-Migration of rhodium via C–H bond activation in catalytic decyanative silylation of nitriles

Supplementary files

Article information

Article type
Communication
Submitted
11 Sep 2012
Accepted
10 Oct 2012
First published
11 Oct 2012

Chem. Commun., 2012,48, 11437-11439

1,5-Migration of rhodium via C–H bond activation in catalytic decyanative silylation of nitriles

M. Tobisu, J. Hasegawa, Y. Kita, H. Kinuta and N. Chatani, Chem. Commun., 2012, 48, 11437 DOI: 10.1039/C2CC36601K

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