Issue 97, 2012
From the journal:

Chemical Communications

Solution mediated phase transformation (RHO to SOD) in porous Co-imidazolate based zeolitic frameworks with high water stability†‡

Bishnu P. Biswal,a   Tamas Pandaa  and  Rahul Banerjee*a  

* Corresponding authors

a Physical/Materials Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, India
E-mail: r.banerjee@ncl.res.in
Fax: +91 2025902535

Abstract

Here we report a highly porous, water stable Co based ZIF [CoNIm (RHO)] and its solution mediated phase transformation to a less porous and water unstable ZIF [CoNIm (SOD)]. CoNIm (RHO) has high Langmuir surface area [2087 m2 g−1] as well as high water adsorption [200 cm3 (STP) g−1] capacity.

Graphical abstract: Solution mediated phase transformation (RHO to SOD) in porous Co-imidazolate based zeolitic frameworks with high water stability

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Article information

DOI
https://doi.org/10.1039/C2CC36651G
Article type
Communication
Submitted
13 Sep 2012
Accepted
18 Oct 2012
First published
18 Oct 2012

Chem. Commun., 2012,48, 11868-11870

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Solution mediated phase transformation (RHO to SOD) in porous Co-imidazolate based zeolitic frameworks with high water stability

B. P. Biswal, T. Panda and R. Banerjee, Chem. Commun., 2012, 48, 11868 DOI: 10.1039/C2CC36651G

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