Neutral tetrathia[22]annulene[2.1.2.1] based field-effect transistors: improved on/off ratio defies ring puckering†
Abstract
New, neutral, slightly puckered aromatic meso-substituted tetrathia[22]annulene[2.1.2.1] macrocyclic architectures display p-type semiconductor behaviour and constitute molecular field-effect transistors with high on/off ratios (8.67 × 106) and high mobility (0.23 cm2 V−1 s−1) in thin films deposited on