Issue 98, 2012
From the journal:

Chemical Communications

A straightforward access to photochromic diarylethene derivatives viapalladium-catalysed direct heteroarylation of 1,2-dichloroperfluorocyclopentene†

Kassem Beydoun,a   Julien Roger,a   Julien Boixel,a   Hubert Le Bozec,a   Véronique Guerchais*a  and  Henri Doucet*a  

* Corresponding authors

a Institut Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes 1 “Organométalliques, Matériaux et Catalyse”, 35042 Rennes Cedex, France
E-mail: henri.doucet@univ-rennes1.fr, veronique.guerchais@univ-rennes1.fr
Tel: +33 (0)2 23 23 63 84

Abstract

A novel and efficient palladium-catalysed direct di-heteroarylation of 1,2-dichloroperfluorocyclopentene with a variety of heteroarenes is reported, giving rise to 1,2-di(heteroaryl)ylperfluorocyclopentene photochromic compounds. The reaction proceeds with thiazoles, thiophenes or furan derivatives and tolerates various substituents.

Graphical abstract: A straightforward access to photochromic diarylethene derivatives via palladium-catalysed direct heteroarylation of 1,2-dichloroperfluorocyclopentene

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Article information

DOI
https://doi.org/10.1039/C2CC37046H
Article type
Communication
Submitted
28 Sep 2012
Accepted
16 Oct 2012
First published
17 Oct 2012

Chem. Commun., 2012,48, 11951-11953

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A straightforward access to photochromic diarylethene derivatives via palladium-catalysed direct heteroarylation of 1,2-dichloroperfluorocyclopentene

K. Beydoun, J. Roger, J. Boixel, H. L. Bozec, V. Guerchais and H. Doucet, Chem. Commun., 2012, 48, 11951 DOI: 10.1039/C2CC37046H

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