Issue 8, 2012
From the journal:

CrystEngComm

Picturing the induced fit of calix[5]arenes upon n-alkylammonium cation binding†‡

Giuseppe Gattuso,a   Anna Notti,a   Sebastiano Pappalardo,b   Melchiorre F. Parisi,*a   Tullio Pilati*cd  and  Giancarlo Terraneoc  

* Corresponding authors

a Dipartimento di Chimica Organica e Biologica, Università di Messina, viale F. Stagno d'Alcontres 31, 98166 Messina, Italy
E-mail: mparisi@unime.it
Fax: +39 090 393895
Tel: +39 090 6765170

b Dipartimento di Scienze Chimiche, Università di Catania, viale A. Doria 6, 95125 Catania, Italy

c NFMLab, Department of Chemistry, Materials and Chemical Engineering, “Giulio Natta”, Politecnico di Milano, via L. Mancinelli 7, 20131 Milan, Italy
E-mail: tullio.pilati@chem.polimi.it
Fax: +39 02 23993180
Tel: +39 02 23993063

d Istituto di Scienze Chimiche e Molecolari—CNR, via Golgi 19, 20133 Milan, Italy

Abstract

The serendipitous crystallization of a 1 : 1 endo-cavity complex between calix[5]arene penta-ester 1a and n-butylammonium ions sheds light on the conformational rearrangement—from cone-in to cone-out—this calixarene family undergoes upon guest inclusion.

Graphical abstract: Picturing the induced fit of calix[5]arenes upon n-alkylammonium cation binding

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CE06719F
Article type
Communication
Submitted
22 Dec 2011
Accepted
02 Feb 2012
First published
02 Feb 2012

CrystEngComm, 2012,14, 2621-2625

Permissions

Request permissions

Picturing the induced fit of calix[5]arenes upon n-alkylammonium cation binding

G. Gattuso, A. Notti, S. Pappalardo, M. F. Parisi, T. Pilati and G. Terraneo, CrystEngComm, 2012, 14, 2621 DOI: 10.1039/C2CE06719F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements