Issue 18, 2012
From the journal:

CrystEngComm

A novel metal–organic framework displaying reversibly shrinking and expanding pore modulation†

Xiao-Ling Li,a   Guang-Zhen Liu,*a   Ling-Yun Xina  and  Li-Ya Wang*ab  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, Henan, P. R. China
E-mail: gzliu@yahoo.com.cn

b College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang, Henan, P. R. China
E-mail: wlya@lynu.edu.cn

Abstract

A dynamically breathable microporous metal–organic framework was solvothermally synthesized and tested by the combination of X-ray diffractions and TG analysis techniques, unambiguously indicating that a reversible dehydration–rehydration process is accompanied by evident contraction and expansion of the pores without losing framework integrity.

Graphical abstract: A novel metal–organic framework displaying reversibly shrinking and expanding pore modulation

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Article information

DOI
https://doi.org/10.1039/C2CE25715G
Article type
Communication
Submitted
09 May 2012
Accepted
23 Jul 2012
First published
23 Jul 2012

CrystEngComm, 2012,14, 5757-5760

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A novel metal–organic framework displaying reversibly shrinking and expanding pore modulation

X. Li, G. Liu, L. Xin and L. Wang, CrystEngComm, 2012, 14, 5757 DOI: 10.1039/C2CE25715G

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