Issue 14, 2012
From the journal:

Dalton Transactions

Two-dimensional assembly of tetrahedral chalcogenide clusters with tetrakis(imidazolyl)borate ligands†‡

Ziyi Chen,a   Daibing Luo,b   Xiuchao Luo,a   Maoping Kanga  and  Zhien Lin*a  

* Corresponding authors

a College of Chemistry, Sichuan University, Chengdu, P. R. China
E-mail: zhienlin@scu.edu.cn
Fax: 86 28 85418451
Tel: 86 28 85412284

b Analytical & Testing Center, Sichuan University, Chengdu, P. R. China

Abstract

A new two-dimensional inorganic–organic hybrid solid, formulated as Cd17S4(SPh)25B(im)4 (SPh = benzenethiolate, im = imidazolate), has been synthesized under solvothermal conditions. The structure features a 63 network with 17-nuclear cadmium clusters linked by B(im)4− ligands. The compound is a semiconductor with the band gap of 2.66 eV and displays a green luminescence upon excitation at 390 nm.

Graphical abstract: Two-dimensional assembly of tetrahedral chalcogenide clusters with tetrakis(imidazolyl)borate ligands

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Article information

DOI
https://doi.org/10.1039/C2DT12043G
Article type
Communication
Submitted
27 Oct 2011
Accepted
24 Nov 2011
First published
12 Dec 2011

Dalton Trans., 2012,41, 3942-3944

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Two-dimensional assembly of tetrahedral chalcogenide clusters with tetrakis(imidazolyl)borate ligands

Z. Chen, D. Luo, X. Luo, M. Kang and Z. Lin, Dalton Trans., 2012, 41, 3942 DOI: 10.1039/C2DT12043G

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