New procedures for the synthesis of [Au(NHC)(OH)] are reported. Initially, a two-step reaction via the digold complex [{Au(NHC)}2(μ-OH)][BF4] was probed, enabling the preparation of the novel [Au(SIPr)(OH)] complex and of its previously reported congener [Au(IPr)(OH)]. After further optimization, a one-step procedure was developed.
![Graphical abstract: Synthetic routes to [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) complexes](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C2DT30294B&imageInfo.ImageIdentifier.Year=2012)
A. Gómez-Suárez, R. S. Ramón, A. M. Z. Slawin and S. P. Nolan, Dalton Trans., 2012, 41, 5461 DOI: 10.1039/C2DT30294B
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
