Issue 27, 2012
From the journal:

Dalton Transactions

Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour†‡

Sylvain Gaillard,ab   Diane Rix,c   Alexandra M. Z. Slawin,a   Jérôme Lacour*c  and  Steven P. Nolan*a  

* Corresponding authors

a EaStCHEM School of Chemistry, University of St Andrews, St Andrews, UK
E-mail: snolan@st-andrews.ac.uk
Fax: (+) 44(0)1334463808

b Laboratoire de Chimie Moléculaire et Thioorganique, UMR 6507, INC3M, FR 3038, ENSICAEN-Université de Caen, 6 bd. Maréchal Juin, 14050 Caen, France

c Département de chimie organique, Université de Genève, 30 quai Ernest Ansermet, Genève 4, Suisse
E-mail: jerome.lacour@unige.ch
Fax: (+) 4122 379 32 15

Abstract

The synthesis and characterization of a new class of cationic (NHC)gold(I) (NHC = N-Heterocyclic carbene) complex containing the phosphate counterions TRISPHAT and TRISPHAT-N have been achieved. The selection of the appropriate hexacoordinated phosphate architecture permits the isolation of complexes bearing an inner or outer sphere anionic counterion.

Graphical abstract: Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour

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Article information

DOI
https://doi.org/10.1039/C2DT30440F
Article type
Communication
Submitted
23 Feb 2012
Accepted
16 May 2012
First published
31 May 2012

Dalton Trans., 2012,41, 8235-8237

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Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour

S. Gaillard, D. Rix, A. M. Z. Slawin, J. Lacour and S. P. Nolan, Dalton Trans., 2012, 41, 8235 DOI: 10.1039/C2DT30440F

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