Issue 23, 2012
From the journal:

Dalton Transactions

Complexes with 3-(pyridin-2-yl)imidazo[1,5-a]pyridineligands by spontaneous dimerization of pyridine-2-carboxaldehyde within the coordination sphere of manganese(ii) in a one-pot reaction†

Celedonio M. Álvarez,a   Lucía Álvarez-Miguel,a   Raúl García-Rodrígueza  and  Daniel Miguel*a  

* Corresponding authors

a GIR MIOMET IU CINQUIMA/Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, C/Prado de la Magdalena s/n., Valladolid, Spain
E-mail: dmsj@qi.uva.es

Abstract

Condensation of two molecules of pyridine-2-carboxaldehyde (pyca), in the presence of MnCl2 and ammonium diethyldithiophosphate, produced, in a one-pot reaction, Mn(II) complexes containing 3-(pyridin-2-yl)imidazo[1,5-a]pyridines as κ2(N,N) chelate ligands which could be easily separated from the metal, this being a convenient way to pyridyl-aza-indolizine heterocycles.

Graphical abstract: Complexes with 3-(pyridin-2-yl)imidazo[1,5-a]pyridine ligands by spontaneous dimerization of pyridine-2-carboxaldehyde within the coordination sphere of manganese(ii) in a one-pot reaction

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2DT30453H
Article type
Paper
Submitted
24 Feb 2012
Accepted
16 Apr 2012
First published
17 Apr 2012

Dalton Trans., 2012,41, 7041-7046

Permissions

Request permissions

Complexes with 3-(pyridin-2-yl)imidazo[1,5-a]pyridine ligands by spontaneous dimerization of pyridine-2-carboxaldehyde within the coordination sphere of manganese(II) in a one-pot reaction

C. M. Álvarez, L. Álvarez-Miguel, R. García-Rodríguez and D. Miguel, Dalton Trans., 2012, 41, 7041 DOI: 10.1039/C2DT30453H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements