Issue 23, 2012
From the journal:

Dalton Transactions

Heteroleptic silver-containing ionic liquids†

Neil R. Brooks,a   Stijn Schaltin,b   Kristof Van Hecke,ac   Luc Van Meervelt,a   Jan Fransaerb  and  Koen Binnemans*a  

* Corresponding authors

a KU Leuven, Department of Chemistry, Celestijnenlaan 200F - bus 2404, B-3001 Leuven, Belgium
E-mail: koen.binnemans@chem.kuleuven.be
Fax: +3216327992
Tel: +3216327446

b KU Leuven, Department of Metallurgy and Materials Engineering, Kasteelpark Arenberg 44 - bus 2450, B-3001 Leuven, Belgium

c Ghent University, Department of Inorganic and Physical Chemistry, Krijgslaan 281 - S3, B-9000 Gent, Belgium

Abstract

The first examples of structurally characterised mixed-ligand metal-containing ionic liquids (ILs) are presented, synthesised by the use of different N-alkylimidazoles. The cations consist of two-coordinate silver(I) centres ligated by two different N-alkylimidazole ligands. It is shown that the resulting ionic liquids have lower melting points than the single ligand ILs.

Graphical abstract: Heteroleptic silver-containing ionic liquids

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Article information

DOI
https://doi.org/10.1039/C2DT30725A
Article type
Communication
Submitted
28 Feb 2012
Accepted
10 Apr 2012
First published
11 Apr 2012

Dalton Trans., 2012,41, 6902-6905

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Heteroleptic silver-containing ionic liquids

N. R. Brooks, S. Schaltin, K. Van Hecke, L. Van Meervelt, J. Fransaer and K. Binnemans, Dalton Trans., 2012, 41, 6902 DOI: 10.1039/C2DT30725A

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