Issue 36, 2012

Synthetic and catalytic intermediates in a magnesium promoted Tishchenko reaction

Abstract

Magnesium-aryloxide and -amide compounds supported by amidinate ligands are accessible in two-steps from a suitable Grignard reagent. Both species are active for the dimerization of benzaldehyde. The slower initiation by the aryloxide was exploited in the isolation of a bis-mesitylaldehyde adduct.

Graphical abstract: Synthetic and catalytic intermediates in a magnesium promoted Tishchenko reaction

Supplementary files

Article information

Article type
Communication
Submitted
02 Jul 2012
Accepted
26 Jul 2012
First published
26 Jul 2012

Dalton Trans., 2012,41, 10930-10933

Synthetic and catalytic intermediates in a magnesium promoted Tishchenko reaction

B. M. Day, W. Knowelden and M. P. Coles, Dalton Trans., 2012, 41, 10930 DOI: 10.1039/C2DT31442H

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