The reaction of pseudo-ortho-4,12-N,N′-diphenyldiamino-[2.2]paracyclophane ((±)-3) with Sn[N(SiMe3)2]2 results in the formation of the monomeric planar chiral N-heterocyclic stannylene (±)-4, featuring a unique [2.2]paracyclophane backbone, which has been characterized by an X-ray diffraction study.
![Graphical abstract: A planar chiral [2.2]paracyclophane derived N-heterocyclic stannylene](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C2DT31497E&imageInfo.ImageIdentifier.Year=2012)
I. Piel, J. V. Dickschat, T. Pape, F. E. Hahn and F. Glorius, Dalton Trans., 2012, 41, 13788 DOI: 10.1039/C2DT31497E
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