Issue 43, 2012

Carboxylated polymers functionalized by cyclodextrins for the stabilization of highly efficient rhodium(0) nanoparticles in aqueous phase catalytic hydrogenation

Abstract

Rhodium(0) nanoparticles stabilized by a polymer containing carboxylate and β-cyclodextrin moieties have high stability and catalytic activity for aqueous hydrogenation reactions of olefins and aromatic substrates. This catalytic system can be recycled and reused without loss of activity. These high catalytic performances can be attributed to conjugated electrostatic interactions (carboxylate groups) and steric interactions (polymer structure and β-cyclodextrin moiety).

Graphical abstract: Carboxylated polymers functionalized by cyclodextrins for the stabilization of highly efficient rhodium(0) nanoparticles in aqueous phase catalytic hydrogenation

Supplementary files

Article information

Article type
Paper
Submitted
18 Jul 2012
Accepted
05 Sep 2012
First published
05 Sep 2012

Dalton Trans., 2012,41, 13359-13363

Carboxylated polymers functionalized by cyclodextrins for the stabilization of highly efficient rhodium(0) nanoparticles in aqueous phase catalytic hydrogenation

S. Noël, B. Léger, R. Herbois, A. Ponchel, S. Tilloy, G. Wenz and E. Monflier, Dalton Trans., 2012, 41, 13359 DOI: 10.1039/C2DT31596C

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