Issue 47, 2012
From the journal:

Dalton Transactions

Soft synthesis of isocyanate-functionalised metal–organic frameworks†

Jenny G. Vitillo,*a   Tristan Lescouet,b   Marie Savonnet,bc   David Farrussengb  and  Silvia Bordigaa  

* Corresponding authors

a Dipartimento di Chimica and NIS Centre of Excellence, Università di Torino, Via Pietro Giuria 7, 10125 Torino and INSTM UdR Torino, Italia
E-mail: jenny.vitillo@unito.it

b IRCELYON, Institut de recherches sur la catalyse et l'environnement de Lyon, Université Lyon 1 – CNRS, 2 avenue Albert Einstein, Villeurbanne Cedex, France

c IFP Energies Nouvelles, BP n°3, Solaize, France

Abstract

We have developed an original synthetic pathway for the conversion of a MIL-68(In)-NH2 metal–organic framework into its corresponding isocyanate (–NCO) derivative. This two-step soft post-modification technique leads to highly porous isostructural materials.

Graphical abstract: Soft synthesis of isocyanate-functionalised metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C2DT31977B
Article type
Communication
Submitted
29 Aug 2012
Accepted
09 Oct 2012
First published
10 Oct 2012

Dalton Trans., 2012,41, 14236-14238

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Soft synthesis of isocyanate-functionalised metal–organic frameworks

J. G. Vitillo, T. Lescouet, M. Savonnet, D. Farrusseng and S. Bordiga, Dalton Trans., 2012, 41, 14236 DOI: 10.1039/C2DT31977B

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