Catalytic interconversion between hydrogen and formic acid at ambient temperature and pressure

Abstract

Interconversion between hydrogen and formic acid in water at ambient temperature and pressure has been made possible by using a [C,N] cyclometalated organoiridium complex, [Ir^III(Cp*)(4-(1H-pyrazol-1-yl-κN²)benzoic acid-κC³)(H₂O)]₂SO₄ [1]₂·SO₄, as an efficient catalyst for both directions depending on pH. Hydrogenation of carbon dioxide by hydrogen occurs in the presence of a catalytic amount of 1 under an atmospheric pressure of H₂ and CO₂ in weakly basic water (pH 7.5) at room temperature, whereas formic acid efficiently decomposes to afford H₂ and CO₂ in the presence of 1 in acidic water (pH 2.8).