Phase evolution, phase transition, and microwave dielectric properties of scheelite structured xBi(Fe1/3Mo2/3)O4–(1−x)BiVO4 (0.0 ≤ x ≤ 1.0) low temperature firing ceramics

Abstract

In the present work, the xBi(Fe_1/3Mo_2/3)O₄–(1−x)BiVO₄ (0.0 ≤ x ≤ 1.0) ceramics were prepared via the solid state reaction method. All the ceramics can be densified at low sintering temperatures around 820 °C. At room temperature, the BiVO₄ type scheelite monoclinic solid solution was formed in ceramic samples with a composition of x ≤ 0.10. When x lies between 0.1 and 0.7, a BiVO₄ scheelite tetragonal phase is formed at room temperature. In the range 0.7 ≤ x < 0.9, the ceramic samples were found to be composites consisting of BiVO₄ type tetragonal and Bi(Fe_1/3Mo_2/3)O₄ type monoclinic scheelite phases, and when x ≥ 0.9, the Bi(Fe_1/3Mo_2/3)O₄ type monoclinic scheelite solid solution was formed. In the BiVO₄ type monoclinic solid solution region, the phase transition to tetragonal phase was studied by in situ Raman and Far-Infrared spectroscopies and by thermal expansion analysis. All of these methods indicated that the phase transition temperature almost linearly decreased from 255 °C for pure BiVO₄ to about −9 °C for x = 0.1 sample. High performance microwave dielectric properties with a high permittivity of about 74.8, high Qf values above 11 500 GHz, and a small temperature coefficient of resonant frequency within +20 ppm per °C in a wide temperature range of 20–140 °C can be obtained in the composite ceramic sample with 60 mol% x = 0.10 composition and 40 mol% x = 0.02 composition. The xBi(Fe_1/3Mo_2/3)O₄–(1−x)BiVO₄ (0.0 ≤ x ≤ 1.0) ceramics might provide useful candidate materials for microwave integrated capacitive devices, such as filters, antennas, etc.