Issue 42, 2012

o-Quinodimethane-methano[60]fullerene and thieno-o-quinodimethane-methano[60]fullerene as efficient acceptor materials for polymer solar cells

Abstract

Two novel 56π-electron fullerenes, o-quinodimethane-methano[60]fullerene (OQMF) and thieno-o-quinodimethane-methano[60]fullerene (TOQMF), were prepared by Diels–Alder reaction between methano[60]fullerene and o-quinodimethane type dienes. These fullerenes possess not only high LUMO levels but also sterically small addends, featuring outstanding performance in polymer solar cells. Up to 5.74% and 5.51% PCEs were achieved for OQMF/P3HT and TOQMF/P3HT solar cells, respectively.

Graphical abstract: o-Quinodimethane-methano[60]fullerene and thieno-o-quinodimethane-methano[60]fullerene as efficient acceptor materials for polymer solar cells

Supplementary files

Article information

Article type
Communication
Submitted
06 Aug 2012
Accepted
18 Sep 2012
First published
20 Sep 2012

J. Mater. Chem., 2012,22, 22374-22377

o-Quinodimethane-methano[60]fullerene and thieno-o-quinodimethane-methano[60]fullerene as efficient acceptor materials for polymer solar cells

G. Ye, S. Chen, Z. Xiao, Q. Zuo, Q. Wei and L. Ding, J. Mater. Chem., 2012, 22, 22374 DOI: 10.1039/C2JM35247H

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