Rotational barriers of biphenyls having heavy heteroatoms as ortho-substituents: experimental and theoretical determination of steric effects†
Abstract
The free energies of
* Corresponding authors
a
Department of Organic Chemistry “A. Mangini”, University of Bologna, Viale Risorgimento 4, Bologna, Italy
E-mail:
andrea.mazzanti@unibo.it
Fax: +39 051 2093654
Tel: +39 051 2093632
b
Chemistry Department, University of Perugia, Via Elce di Sotto 10, Perugia, Italy
E-mail:
ruzzchor@unipg.it
Fax: +39 075 5855262
Tel: +39 075 5855543
c
Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale (EPFL–BCh), Lausanne, Switzerland
E-mail:
manfred.schlosser@epfl.ch
Tel: +41 021 6939351
The free energies of
L. Lunazzi, M. Mancinelli, A. Mazzanti, S. Lepri, R. Ruzziconi and M. Schlosser, Org. Biomol. Chem., 2012, 10, 1847 DOI: 10.1039/C1OB06688A
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