Issue 3, 2012
From the journal:

Organic & Biomolecular Chemistry

The design and synthesis of novel IBiox N-heterocyclic carbeneligands derived from substituted amino-indanols†

Jean-Noël Levy,a   Christopher M. Latham,b   Loïc Roisin,a   Nadine Kandziora,a   Paolo Di Fruscia,a   Andrew J. P. White,a   Simon Woodwardb  and  Matthew J. Fuchter*a  

* Corresponding authors

a Department of Chemistry, Imperial College London, London, United Kingdom
E-mail: m.fuchter@imperial.ac.uk

b School of Chemistry, The University of Nottingham, Nottingham, United Kingdom

Abstract

A synthetic route towards a number of novel IBiox N-heterocyclic carbene (NHC) ligands has been developed. The resulting ligands have restricted flexibility and high steric demand. Preliminary studies have shown these ligands to give high levels of asymmetric induction in the copper-free allylic alkylation of cinnamyl bromide.

Graphical abstract: The design and synthesis of novel IBiox N-heterocyclic carbene ligands derived from substituted amino-indanols

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Article information

DOI
https://doi.org/10.1039/C1OB06780J
Article type
Communication
Submitted
22 Oct 2011
Accepted
14 Nov 2011
First published
16 Nov 2011

Org. Biomol. Chem., 2012,10, 512-515

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The design and synthesis of novel IBiox N-heterocyclic carbene ligands derived from substituted amino-indanols

J. Levy, C. M. Latham, L. Roisin, N. Kandziora, P. D. Fruscia, A. J. P. White, S. Woodward and M. J. Fuchter, Org. Biomol. Chem., 2012, 10, 512 DOI: 10.1039/C1OB06780J

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