Issue 23, 2012

Hypervalent iodine mediated synthesis of carbamate protected p-quinone monoimine ketals and p-benzoquinone monoketals

Abstract

A simple and efficient method for the synthesis of p-quinone monoimide ketals and p-benzoquinone monoketals by using a hypervalent iodine reagent, diacetoxyiodobenzene, has been developed. These two types of ketals are achieved from a single starting material by varying the reaction conditions.

Graphical abstract: Hypervalent iodine mediated synthesis of carbamate protected p-quinone monoimine ketals and p-benzoquinone monoketals

Supplementary files

Article information

Article type
Paper
Submitted
12 Jan 2012
Accepted
03 Apr 2012
First published
08 May 2012

Org. Biomol. Chem., 2012,10, 4549-4553

Hypervalent iodine mediated synthesis of carbamate protected p-quinone monoimine ketals and p-benzoquinone monoketals

N. Bodipati and R. K. Peddinti, Org. Biomol. Chem., 2012, 10, 4549 DOI: 10.1039/C2OB25089F

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