Issue 34, 2012
From the journal:

Organic & Biomolecular Chemistry

Palladium-catalyzed α-regioselective allylic amination of Morita–Baylis–Hillman acetates with simple aromatic amines†

Yan Wang,ab   Li Liu,*a   Dong Wanga  and  Yong-Jun Chena  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: lliu@iccas.ac.cn
Fax: +86 010 6255 4449
Tel: +86 010 6255 4614

b Graduate School of Chinese Academy of Sciences, Beijing 100049, China

Abstract

An efficient allylic amination of Morita–Baylis–Hillman acetates with simple aromatic amines provided good yields with excellent α-regioselectivity (up to exclusive α-product) under the catalysis of Pd2(dba)3/ferrocene-type diphosphine ligand.

Graphical abstract: Palladium-catalyzed α-regioselective allylic amination of Morita–Baylis–Hillman acetates with simple aromatic amines

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Article information

DOI
https://doi.org/10.1039/C2OB25976A
Article type
Paper
Submitted
21 May 2012
Accepted
26 Jun 2012
First published
27 Jun 2012

Org. Biomol. Chem., 2012,10, 6908-6913

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Palladium-catalyzed α-regioselective allylic amination of Morita–Baylis–Hillman acetates with simple aromatic amines

Y. Wang, L. Liu, D. Wang and Y. Chen, Org. Biomol. Chem., 2012, 10, 6908 DOI: 10.1039/C2OB25976A

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