Issue 36, 2012
From the journal:

Organic & Biomolecular Chemistry

Palladium-catalyzed atom transfer radical cyclization of unactivated alkyl iodide†

Hui Liu,a   Zongjun Qiaoa  and  Xuefeng Jiang*a  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, 3663 North Zhongshan Lu, Shanhai 200062, P.R. China
E-mail: xfjiang@chem.ecnu.edu.cn
Tel: +86-21-52133654

Abstract

A palladium-catalyzed atom transfer cyclization of unactivated alkyl iodide has been developed. A radical chain mechanism has been proposed for this transformation, which might not involve an alkylpalladium intermediate.

Graphical abstract: Palladium-catalyzed atom transfer radical cyclization of unactivated alkyl iodide

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Article information

DOI
https://doi.org/10.1039/C2OB25990G
Article type
Communication
Submitted
22 May 2012
Accepted
26 Jul 2012
First published
01 Aug 2012

Org. Biomol. Chem., 2012,10, 7274-7277

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Palladium-catalyzed atom transfer radical cyclization of unactivated alkyl iodide

H. Liu, Z. Qiao and X. Jiang, Org. Biomol. Chem., 2012, 10, 7274 DOI: 10.1039/C2OB25990G

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