Issue 43, 2012

Hypoiodous acid initiated rearrangement of tertiary propargylic alcohols to α-iodoenones

Abstract

In the presence of an oxidant, sodium iodide is converted into hypoiodous acid which effects the rearrangement of tertiary propargylic alcohols to α-iodoenones in good yields.

Graphical abstract: Hypoiodous acid initiated rearrangement of tertiary propargylic alcohols to α-iodoenones

Supplementary files

Article information

Article type
Communication
Submitted
07 Jun 2012
Accepted
02 Oct 2012
First published
03 Oct 2012
This article is Open Access

Org. Biomol. Chem., 2012,10, 8590-8592

Hypoiodous acid initiated rearrangement of tertiary propargylic alcohols to α-iodoenones

W. J. Moran and A. Rodríguez, Org. Biomol. Chem., 2012, 10, 8590 DOI: 10.1039/C2OB26360B

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