Issue 4, 2012
From the journal:

RSC Advances

Solvent based selectivity in the synthesis of di(2-aryl-1H-3-indolyl) sulfides and 1-aryl-2-[(2-aryl-1H-3-indolyl)sulfanyl]-1-ethanones†

Selvam Chitra,a   Nidhin Paul,b   Shanmugam Muthusubramanian*b  and  Paramasivam Manisankar*a  

* Corresponding authors

a Department of Industrial Chemistry, Alagappa University, Karaikudi—630 003, Tamil Nadu, India
E-mail: muthumanian2001@yahoo.com

b Department of Organic Chemistry, School of Chemistry, Madurai Kamaraj University, Madurai, India
E-mail: pms11@rediffmail.com

Abstract

The commendable product selectivity exhibited by the solvents during the reaction of 2-[(2-oxo-2-arylethyl)sulfanyl]-1-aryl-1-ethanones with phenylhydrazine hydrochloride yielding exclusively 1-aryl-2-[(2-aryl-1H-3-indolyl)sulfanyl]-1-ethanones in THF and di(2-aryl-1H-3-indolyl) sulfides in ethanol is described.

Graphical abstract: Solvent based selectivity in the synthesis of di(2-aryl-1H-3-indolyl) sulfides and 1-aryl-2-[(2-aryl-1H-3-indolyl)sulfanyl]-1-ethanones

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Article information

DOI
https://doi.org/10.1039/C1RA00878A
Article type
Paper
Submitted
12 Oct 2011
Accepted
02 Nov 2011
First published
15 Dec 2011

RSC Adv., 2012,2, 1432-1438

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Solvent based selectivity in the synthesis of di(2-aryl-1H-3-indolyl) sulfides and 1-aryl-2-[(2-aryl-1H-3-indolyl)sulfanyl]-1-ethanones

S. Chitra, N. Paul, S. Muthusubramanian and P. Manisankar, RSC Adv., 2012, 2, 1432 DOI: 10.1039/C1RA00878A

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