Issue 3, 2012
From the journal:

RSC Advances

The alcohol-mediated reduction of CO2 and NaHCO3 into formate: a hydrogen transfer reduction of NaHCO3 with glycerine under alkaline hydrothermal conditions†

Zheng Shen,ac   Yalei Zhang*a  and  Fangming Jin*b  

* Corresponding authors

a State Key Laboratory of Pollution Control and Resources Reuse, Key Laboratory of Yangtze River Water Environment of MOE, College of Environmental Science and Engineering, Tongji University, Shanghai, China
E-mail: zhangyalei@tongji.edu.cn;

b School of Environmental Science and Engineering, Shanghai Jiao Tong University, China
E-mail: fmjin@sjtu.edu.cn

c State Key Laboratory of Catalysis Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.

Abstract

A hydrothermal method for the hydrogen-transfer reduction of CO2 or NaHCO3 is presented. This process uses glycerine as a reducing agent, which is ultimately converted to lactate, and can convert NaHCO3 into formate in about a 90% yield with respect to the initial amount of glycerine.

Graphical abstract: The alcohol-mediated reduction of CO2 and NaHCO3 into formate: a hydrogen transfer reduction of NaHCO3 with glycerine under alkaline hydrothermal conditions

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Article information

DOI
https://doi.org/10.1039/C1RA00886B
Article type
Communication
Submitted
13 Oct 2011
Accepted
03 Nov 2011
First published
01 Dec 2011

RSC Adv., 2012,2, 797-801

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The alcohol-mediated reduction of CO2 and NaHCO3 into formate: a hydrogen transfer reduction of NaHCO3 with glycerine under alkaline hydrothermal conditions

Z. Shen, Y. Zhang and F. Jin, RSC Adv., 2012, 2, 797 DOI: 10.1039/C1RA00886B

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