Issue 30, 2012
From the journal:

RSC Advances

Killing double bonds softly: the reduction of polymer-bound alkenes†

Daniel Fürniss,a   Ute Schepersb  and  Stefan Bräse*ab  

* Corresponding authors

a Institute of Organic Chemistry, Karlsruhe Institute of Technology, Fritz-Haber-Weg 6, 76131 Karlsruhe, Germany
E-mail: stefan.braese@kit.edu
Fax: +49 721 608-48581
Tel: +49 721 608-42903

b Institute of Toxicology and Genetics, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract

Alkenes can be reduced through “transfer hydrogenation” with dimethylamine-borane adduct and Wilkinson's catalyst. This reaction can also be carried out by solid-phase synthesis as a heterogeneous reaction. Furthermore, the behaviour of various functional groups under hydrogenation conditions was tested.

Graphical abstract: Killing double bonds softly: the reduction of polymer-bound alkenes

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Article information

DOI
https://doi.org/10.1039/C2RA22189F
Article type
Paper
Submitted
18 Sep 2012
Accepted
19 Sep 2012
First published
19 Sep 2012

RSC Adv., 2012,2, 11273-11278

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Killing double bonds softly: the reduction of polymer-bound alkenes

D. Fürniss, U. Schepers and S. Bräse, RSC Adv., 2012, 2, 11273 DOI: 10.1039/C2RA22189F

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