“Push effect” of sulfur coordination: promoting the breaking of C(sp2)–I bond by pincer thioimido-Pd(II) complexes

Jing Liu; Yi Deng; Caitao Lin; Aiwen Lei

doi:10.1039/C2SC00888B

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“Push effect” of sulfur coordination: promoting the breaking of C(sp²)–I bond by pincer thioimido-Pd(ii) complexes†

Jing Liu,^a Yi Deng,^a Caitao Lin^a and Aiwen Lei*^ab

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* Corresponding authors

^a College of Chemistry and Molecular Sciences, Wuhan University, P. R. China
E-mail: aiwenlei@whu.edu.cn
Web: http://www.chem.whu.edu.cn/GCI_WebSite/main.htm
Fax: (+86)-27-68754067

^b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou

Abstract

Aryl–iodo bond cleavage by pincer thioimido-Pd(II) complex was demonstrated by in situ IR and X-ray analysis. Stoichiometric reactions indicated the crucial role of substrate sulfur coordination to the Pd centre. Possible mechanisms were proposed and catalytic reaction was developed.

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Article information

DOI: https://doi.org/10.1039/C2SC00888B
Article type: Edge Article
Submitted: 07 Nov 2011
Accepted: 03 Jan 2012
First published: 05 Jan 2012

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Chem. Sci., 2012,3, 1211-1214

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“Push effect” of sulfur coordination: promoting the breaking of C(sp²)–I bond by pincer thioimido-Pd(II) complexes

J. Liu, Y. Deng, C. Lin and A. Lei, Chem. Sci., 2012, 3, 1211 DOI: 10.1039/C2SC00888B

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