Issue 5, 2012
From the journal:

Chemical Science

Direct oxidative arylationvia rhodium-catalyzed C–C bond cleavage of secondary alcohols with arylsilanes†

Kang Chen,a   Hu Li,a   Yang Li,a   Xi-Sha Zhang,a   Zhi-Quan Lei*ac  and  Zhang-Jie Shiab  

* Corresponding authors

a Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Green Chemistry Center, Peking University, Beijing, China
E-mail: zshi@pku.edu.cn
Web: http://www.shigroup.cn
Fax: +86-10-6276-0890

b State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai, China

c Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, Sichuan, China

Abstract

An unprecedented example of sequential pyridinyl directed C–C cleavage of secondary alcohols/oxidative arylation with arylsilanes via Rh(III) catalysis is reported. Preliminary studies indicated that the arylation initiated from Rh(III)-catalyzed C–C cleavage, and a 5-membered rhodacycle was involved as a key intermediate.

Graphical abstract: Direct oxidative arylation via rhodium-catalyzed C–C bond cleavage of secondary alcohols with arylsilanes

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Article information

DOI
https://doi.org/10.1039/C2SC00923D
Article type
Edge Article
Submitted
15 Nov 2011
Accepted
18 Jan 2012
First published
19 Jan 2012

Chem. Sci., 2012,3, 1645-1649

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Direct oxidative arylation via rhodium-catalyzed C–C bond cleavage of secondary alcohols with arylsilanes

K. Chen, H. Li, Y. Li, X. Zhang, Z. Lei and Z. Shi, Chem. Sci., 2012, 3, 1645 DOI: 10.1039/C2SC00923D

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