Issue 7, 2012
From the journal:

Chemical Science

Binuclear rare-earth polyhydride complexes bearing both terminal and bridging hydride ligands†

Jianhua Cheng,a   Haiyu Wang,a   Masayoshi Nishiuraa  and  Zhaomin Hou*a  

* Corresponding authors

a Organometallic Chemistry Laboratory and Advanced Catalyst Research Team, RIKEN Advanced Science Institute, 2–1 Hirosawa, Wako, Japan
E-mail: houz@riken.jp
Fax: (+81) 48-462-4665

Abstract

The first binuclear rare-earth tetrahydride complexes [(NCN)LnH2]2(THF)3 (1-Ln; Ln[double bond, length as m-dash]Y, Lu; NCN[double bond, length as m-dash]PhC(NC6H3iPr2-2,6)2) bearing both terminal and bridging hydride ligands were obtained by hydrogenolysis of the dialkyl precursors. These novel binuclear hydride complexes underwent unique Ln-H addition reactions with various unsaturated compounds such as 2,6-dimethylphenyl isocyanide, diphenylacetylene and 1,4-diphenyl-1,3-butadiyne.

Graphical abstract: Binuclear rare-earth polyhydride complexes bearing both terminal and bridging hydride ligands

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Article information

DOI
https://doi.org/10.1039/C2SC20300F
Article type
Edge Article
Submitted
09 Mar 2012
Accepted
03 Apr 2012
First published
03 Apr 2012

Chem. Sci., 2012,3, 2230-2233

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Binuclear rare-earth polyhydride complexes bearing both terminal and bridging hydride ligands

J. Cheng, H. Wang, M. Nishiura and Z. Hou, Chem. Sci., 2012, 3, 2230 DOI: 10.1039/C2SC20300F

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