Issue 2, 2013
From the journal:

Chemical Communications

Direct synthesis of alkylsilanes by platinum-catalyzed coupling of hydrosilanes and iodoalkanes†

Hikaru Inubushi,a   Hitoshi Kondo,a   Aldes Lesbani,a   Mariko Miyachi,a   Yoshinori Yamanoi*a  and  Hiroshi Nishihara*a  

* Corresponding authors

a Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Tokyo 113-0033, Bunkyo-ku, Japan
E-mail: yamanoi@chem.s.u-tokyo.ac.jp, nisihara@chem.s.u-tokyo.ac.jp
Fax: +81 3 5841 8063

Abstract

Alkyl iodides and tertiary silanes were successfully coupled with good functional group tolerance using a Pt(P(tBu)3)2/(iPr)2EtN/CH3CN system. The utility of the methodology is demonstrated by the synthesis of silafluofen, a Si-containing insecticide.

Graphical abstract: Direct synthesis of alkylsilanes by platinum-catalyzed coupling of hydrosilanes and iodoalkanes

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Article information

DOI
https://doi.org/10.1039/C2CC35150A
Article type
Communication
Submitted
18 Jul 2012
Accepted
01 Oct 2012
First published
16 Oct 2012

Chem. Commun., 2013,49, 134-136

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Direct synthesis of alkylsilanes by platinum-catalyzed coupling of hydrosilanes and iodoalkanes

H. Inubushi, H. Kondo, A. Lesbani, M. Miyachi, Y. Yamanoi and H. Nishihara, Chem. Commun., 2013, 49, 134 DOI: 10.1039/C2CC35150A

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