Issue 8, 2013
From the journal:

Chemical Communications

Preparation and study of an f,f,f′,f′′ covalently linked tetranuclear hetero-trimetallic complex – a europium, terbium, dysprosium triad†

Thomas Just Sørensen,*ab   Manuel Tropiano,a   Octavia A. Blackburn,a   James A. Tilney,a   Alan M. Kenwrightc  and  Stephen Faulkner*a  

* Corresponding authors

a Chemical Research Laboratory, Oxford University, 12 Mansfield Road, Oxford OX1 3TA, England
E-mail: Stephen.Faulkner@chem.ox.ac.uk
Tel: +44 (0)1865 285148

b Nano-Science Center and Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 København Ø, Denmark
E-mail: TJS@chem.ku.dk
Fax: +45 35320214
Tel: +45 35320213

c Department of Chemistry, University of Durham, South Road, Durham DH1 3LE, UK

Abstract

A heterotrimetallic tetranuclear lanthanide complex containing two dysprosium ions, a terbium ion and a europium ion has been prepared by coupling three kinetically stable complexes together using the Ugi reaction. The covalently linked trimetallic system exhibits luminescence from all the different lanthanide centres.

Graphical abstract: Preparation and study of an f,f,f′,f′′ covalently linked tetranuclear hetero-trimetallic complex – a europium, terbium, dysprosium triad

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Article information

DOI
https://doi.org/10.1039/C2CC35931F
Article type
Communication
Submitted
16 Aug 2012
Accepted
06 Dec 2012
First published
07 Dec 2012

Chem. Commun., 2013,49, 783-785

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Preparation and study of an f,f,f′,f′′ covalently linked tetranuclear hetero-trimetallic complex – a europium, terbium, dysprosium triad

T. J. Sørensen, M. Tropiano, O. A. Blackburn, J. A. Tilney, A. M. Kenwright and S. Faulkner, Chem. Commun., 2013, 49, 783 DOI: 10.1039/C2CC35931F

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