Issue 7, 2013
From the journal:

Chemical Communications

Chirality transfer based on reversible C–C bond formation/breaking in nickel(ii) complexes†

Tatsuya Kawamoto,*a   Narumi Suzuki,a   Takeshi Ono,a   Dafei Gongb  and  Takumi Konnob  

* Corresponding authors

a Department of Chemistry, Kanagawa University, Hiratsuka, Japan
E-mail: kaw@kanagawa-u.ac.jp

b Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Japan

Abstract

The reaction of (1R)-(−)-myrtenal-derived benzothiazoline with nickel(II) acetate in ethanol exclusively gave a Schiff base-type nickel(II) complex having M helical configurational myrtenyl arms, which is reversibly converted to a non-innocent-type complex having additional S,S configurational asymmetric carbon centres.

Graphical abstract: Chirality transfer based on reversible C–C bond formation/breaking in nickel(ii) complexes

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Article information

DOI
https://doi.org/10.1039/C2CC36332A
Article type
Communication
Submitted
31 Aug 2012
Accepted
08 Oct 2012
First published
23 Oct 2012

Chem. Commun., 2013,49, 668-670

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Chirality transfer based on reversible C–C bond formation/breaking in nickel(II) complexes

T. Kawamoto, N. Suzuki, T. Ono, D. Gong and T. Konno, Chem. Commun., 2013, 49, 668 DOI: 10.1039/C2CC36332A

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