Issue 39, 2013

[Cu30I16(mtpmt)1210-S4)]: an unusual 30-membered copper(i) cluster derived from the C–S bond cleavage and its use in heterogeneous catalysis

Abstract

The Cu(I)-mediated C–S bond cleavage of 5-methyl-4-(p-tolyl)pyrimidine-2-thiol (mtpmtH) gave one 30-nuclear cluster [Cu30I16(mtpmt)1210-S4)], one polymeric complex [(bmtpms)Cu-(μ-I)]n and one tetranuclear complex [(bmptmds){Cu(μ-I)}2]2; the 30-nuclear cluster displayed excellent catalytic performances in the coupling reactions of N-heterocycles and arylboronic acids and could be recycled and reused.

Graphical abstract: [Cu30I16(mtpmt)12(μ10-S4)]: an unusual 30-membered copper(i) cluster derived from the C–S bond cleavage and its use in heterogeneous catalysis

Supplementary files

Article information

Article type
Communication
Submitted
12 Aug 2012
Accepted
11 Oct 2012
First published
19 Oct 2012

Chem. Commun., 2013,49, 4259-4261

[Cu30I16(mtpmt)1210-S4)]: an unusual 30-membered copper(I) cluster derived from the C–S bond cleavage and its use in heterogeneous catalysis

H. Li, W. Zhao, H. Li, Z. Xu, W. Wang and J. Lang, Chem. Commun., 2013, 49, 4259 DOI: 10.1039/C2CC36736J

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