Issue 39, 2013
From the journal:

Chemical Communications

Formal γ-alkynylation of ketonesvia Pd-catalyzed C–C cleavage†‡

Asraa Ziadi,a   Arkaitz Correaa  and  Ruben Martin*a  

* Corresponding authors

a Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, Tarragona, Spain
E-mail: rmartinromo@iciq.es
Tel: +34 977920248

Abstract

A formal γ-alkynylation of ketones via Pd-catalyzed C–C bond-cleavage is presented. The method allows for the coupling of tert-cyclobutanols and bromoacetylenes, giving access to versatile alkynes that are beyond reach otherwise.

Graphical abstract: Formal γ-alkynylation of ketones via Pd-catalyzed C–C cleavage

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Article information

DOI
https://doi.org/10.1039/C2CC37281A
Article type
Communication
Submitted
05 Oct 2012
Accepted
29 Oct 2012
First published
30 Oct 2012

Chem. Commun., 2013,49, 4286-4288

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Formal γ-alkynylation of ketones via Pd-catalyzed C–C cleavage

A. Ziadi, A. Correa and R. Martin, Chem. Commun., 2013, 49, 4286 DOI: 10.1039/C2CC37281A

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