Probing self-assembled 1,3,5-benzenetrisamides in isotactic polypropylene by 13C DQ solid-state NMR spectroscopy

Marko Schmidt; Johannes J. Wittmann; Roman Kress; Hans-Werner Schmidt; Jürgen Senker

doi:10.1039/C2CC37384J

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Probing self-assembled 1,3,5-benzenetrisamides in isotactic polypropylene by ¹³C DQ solid-state NMR spectroscopy†

Marko Schmidt,^a Johannes J. Wittmann,^a Roman Kress,^b Hans-Werner Schmidt^b and Jürgen Senker*^a

Author affiliations

* Corresponding authors

^a Inorganic Chemistry III, University of Bayreuth, Universitätsstr. 30, Bayreuth, Germany
E-mail: juergen.senker@uni-bayreuth.de
Fax: +49 (0)921/55-2788
Tel: +49 (0)921/55-2531

^b Macromolecular Chemistry I, University of Bayreuth, Universitätsstr. 30, Bayreuth, Germany
E-mail: hans-werner.schmidt@uni-bayreuth.de
Fax: +49 (0)921/55-3206
Tel: +49 (0)921/55-3200

Abstract

Using ¹³C double quantum solid-state NMR spectroscopy, we were able to observe nuclei of a supramolecular BTA based additive on the nanoscale in a matrix of i-PP at a concentration of only 0.09 wt%. These nuclei exhibit the analogous structural features as the crystalline phase of the neat additive.

Download options Please wait...

Supplementary files

Supplementary information PDF (612K)

Article information

DOI: https://doi.org/10.1039/C2CC37384J
Article type: Communication
Submitted: 16 Aug 2012
Accepted: 08 Nov 2012
First published: 22 Nov 2012

Download Citation

Chem. Commun., 2013,49, 267-269

Permissions

Request permissions

Probing self-assembled 1,3,5-benzenetrisamides in isotactic polypropylene by ¹³C DQ solid-state NMR spectroscopy

M. Schmidt, J. J. Wittmann, R. Kress, H. Schmidt and J. Senker, Chem. Commun., 2013, 49, 267 DOI: 10.1039/C2CC37384J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications