Issue 7, 2013
From the journal:

Chemical Communications

Rhodium-catalyzed tandem Pauson–Khand type reactions of 1,4-enynes tethered by a cyclopropyl group†

Gen-Qiang Chena  and  Min Shi*a  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, P. R. China
E-mail: mshi@mail.sioc.ac.cn
Fax: +86-21-64166128

Abstract

The tandem Pauson–Khand type reactions of 1,4-enynes tethered by a cyclopropyl group with two molecules of CO proceed smoothly in the presence of [Rh(CO)2Cl]2 under a CO atmosphere to give the corresponding 6-hydroxy-2,3-dihydro-1H-inden-1-one derivatives in moderate yields under mild conditions.

Graphical abstract: Rhodium-catalyzed tandem Pauson–Khand type reactions of 1,4-enynes tethered by a cyclopropyl group

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Article information

DOI
https://doi.org/10.1039/C2CC37587G
Article type
Communication
Submitted
18 Oct 2012
Accepted
26 Nov 2012
First published
27 Nov 2012

Chem. Commun., 2013,49, 698-700

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Rhodium-catalyzed tandem Pauson–Khand type reactions of 1,4-enynes tethered by a cyclopropyl group

G. Chen and M. Shi, Chem. Commun., 2013, 49, 698 DOI: 10.1039/C2CC37587G

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