Issue 6, 2013
From the journal:

Chemical Communications

A redox-active luminescent ytterbium based single molecule magnet†

Fabrice Pointillart,*a   Boris Le Guennic,a   Stéphane Golhen,a   Olivier Cador,a   Olivier Mauryb  and  Lahcène Ouahaba  

* Corresponding authors

a Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS, Université de Rennes 1, 263 Avenue du Général Leclerc, 35042 Rennes Cedex, France
E-mail: fabrice.pointillart@univ-rennes1.fr

b Laboratoire de Chimie, UMR 5182 CNRS-ENS Lyon-Université Lyon 1, 46 Allée d'Italie, 69364 Lyon Cedex 07, France

Abstract

A redox active dinuclear complex [Yb(tta)2(L1)(L2)]2·1.4(CH2Cl2) displays single molecule magnet behaviour with MJ = ±7/2 ground state. The anisotropic barrier Δ is evaluated by the three dc data fit, ac analysis and emission spectrum demonstrating the correlation between magnetic and optical properties.

Graphical abstract: A redox-active luminescent ytterbium based single molecule magnet

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Article information

DOI
https://doi.org/10.1039/C2CC37635K
Article type
Communication
Submitted
19 Oct 2012
Accepted
26 Nov 2012
First published
27 Nov 2012

Chem. Commun., 2013,49, 615-617

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A redox-active luminescent ytterbium based single molecule magnet

F. Pointillart, B. L. Guennic, S. Golhen, O. Cador, O. Maury and L. Ouahab, Chem. Commun., 2013, 49, 615 DOI: 10.1039/C2CC37635K

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