Issue 5, 2013
From the journal:

Chemical Communications

Synthesis and characterization of a structure H hydrate formed with carbon dioxide and 3,3-dimethyl-2-butanone†

Kyoichi Tezuka,a   Renkai Shen,a   Taku Watanabe,a   Satoshi Takeya,b   Saman Alavi,c   John A. Ripmeesterc  and  Ryo Ohmura*a  

* Corresponding authors

a Department of Mechanical Engineering, Keio University, 3-14-1 Hiyoshi, Kohoku-Ku, Yokohama, Japan
E-mail: rohmura@mech.keio.ac.jp
Tel: +81-45-566-1813

b National Institute of Advanced industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Japan

c Measurement Science and Standards, National Research Council of Canada, 100 Sussex Drive, Ontario K1A 0R6, Ottawa, Canada

Abstract

Experiments were carried out to synthesize and characterize a structure H clathrate hydrate containing CO2 and 3,3-dimethyl-2-butanone (pinacolone) by means of phase equilibrium and powder X-ray diffraction measurements. Molecular dynamics simulations of this structure H hydrate were performed to understand the nature of guest–host molecular interactions.

Graphical abstract: Synthesis and characterization of a structure H hydrate formed with carbon dioxide and 3,3-dimethyl-2-butanone

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Article information

DOI
https://doi.org/10.1039/C2CC37717A
Article type
Communication
Submitted
24 Oct 2012
Accepted
14 Nov 2012
First published
15 Nov 2012

Chem. Commun., 2013,49, 505-507

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Synthesis and characterization of a structure H hydrate formed with carbon dioxide and 3,3-dimethyl-2-butanone

K. Tezuka, R. Shen, T. Watanabe, S. Takeya, S. Alavi, J. A. Ripmeester and R. Ohmura, Chem. Commun., 2013, 49, 505 DOI: 10.1039/C2CC37717A

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