Issue 21, 2013

Unbridged Au(ii)–Au(ii) bonds are theoretically allowed

Abstract

The bonding in the unbridged closed-shell Au(II)–Au(II) dimers X4Au2(C5H5N)2, X = H, F–I and CF3, is analyzed and the short Au–Au bonds around 250 pm are reproduced by a novel 6s6pz5dxy hybridization.

Graphical abstract: Unbridged Au(ii)–Au(ii) bonds are theoretically allowed

Supplementary files

Article information

Article type
Communication
Submitted
30 Oct 2012
Accepted
03 Jan 2013
First published
04 Jan 2013
This article is Open Access
Creative Commons BY license

Chem. Commun., 2013,49, 2103-2105

Unbridged Au(II)–Au(II) bonds are theoretically allowed

X. Xiong and P. Pyykkö, Chem. Commun., 2013, 49, 2103 DOI: 10.1039/C2CC37875B

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