Unprecedented chemical transformation: crystallographic evidence for 1,1,2,2-tetrahydroxyethane captured within an Fe6Dy3 single molecule magnet

Sebastian Schmidt; Denis Prodius; Valeriu Mereacre; George E. Kostakis; Annie K. Powell

doi:10.1039/C2CC38006D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Unprecedented chemical transformation: crystallographic evidence for 1,1,2,2-tetrahydroxyethane captured within an Fe₆Dy₃ single molecule magnet†

Sebastian Schmidt,^a Denis Prodius,*^ab Valeriu Mereacre,^a George E. Kostakis^c and Annie K. Powell*^ac

Author affiliations

* Corresponding authors

^a Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76128 Karlsruhe, Germany
E-mail: annie.powell@kit.edu
Fax: +49 721-608-48142
Tel: +49 721-608-42135

^b Institute of Chemistry of the Academy of Sciences of Moldova, Academiei str. 3, MD-2028 Chisinau, Moldova
E-mail: denis.prodius@kit.edu
Fax: +373 22 739722
Tel: +373 22 739954

^c Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract

A nonanuclear {Fe₆Dy₃} coordination cluster displaying SMM behaviour in which an unprecedented chemical transformation provides structural information for the existence of 1,1,2,2-tetrahydroxyethane is reported.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C2CC38006D
Article type: Communication
Submitted: 05 Nov 2012
Accepted: 06 Dec 2012
First published: 06 Dec 2012

Download Citation

Chem. Commun., 2013,49, 1696-1698

Permissions

Request permissions

Unprecedented chemical transformation: crystallographic evidence for 1,1,2,2-tetrahydroxyethane captured within an Fe₆Dy₃ single molecule magnet

S. Schmidt, D. Prodius, V. Mereacre, G. E. Kostakis and A. K. Powell, Chem. Commun., 2013, 49, 1696 DOI: 10.1039/C2CC38006D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications